Solvent effects on the intrinsic enhancement factors of the triplet exciplex generated by photoinduced electron transfer reaction between eosin Y and duroquinone

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Solvent e ects on the intrinsic enhancement factors of the triplet exciplex generated by photoinduced electron transfer reaction between eosin Y and duroquinone

TAKASHI TACHIKAWA, YASUHIRO KOBORI, KIMIO AKIYAMA, AKIO KATSUKI, YOSHIHARU USUI, ULRICH E. STEINER and SHOZO TERO-KUBOTA* 1 Institute of Multidisplinary Research for Advanced Materials, Tohoku University, Sendai, 980-8577, Japan Department of Chemistry, Faculty of Education, Shinshu University, Nagano, 389-5144, Japan Department of Environmental Sciences, Faculty of Science, Ibaraki University,...

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Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone

The spin dynamics of the duroquinone anion radical generated by photoinduced electron transfer reactions from triplet erythrosin B to duroquinone has been studied by using transient absorption and pulsed FT-EPR spectroscopy. Triplet exciplex formation as the reaction intermediate is verified by the observation of spin–orbit coupling induced electron spin polarization. The kinetic parameters for...

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ژورنال

عنوان ژورنال: Molecular Physics

سال: 2002

ISSN: 0026-8976,1362-3028

DOI: 10.1080/00268970110117962